Bondage babe ... Angelina Jolie is looking for Mr Right to tie her up.

The Hollywood vamp confessed to US women's magazine Allure she was waiting for Mr Right to tie her up during sex and said she had been busy keeping two lovers.

The 29-year-old actress explained she had yet to meet a man she trusted enough to try bonding over bondage but was happy to wait for the right man for the job.

"I've never been tied up. I have a feeling the person that does it will be the one. I think that's what I'd like," she revealed.

The feline-eyed beauty also chatted frankly about sharing her love with "mainly two close lovers", although she refused to name the lucky pair she cryptically called them "professional friends".

The brunette bombshell who has been married twice - to British actor Jonny Lee Miller in 1996 and most recently to Oscar-winning actor Billy Bob Thornton - also said she liked to push "boundaries" when it came to lovers because it made her feel sexy.

"A lot of my relationships just weren't honest enough. So I took them down different paths toward violence or wildness ... to try to find somebody to hold me down and make me feel.

"S&M sex can be misinterpreted as violence. It's really about trust. I like to push boundaries, both emotional and sexual, with another person. That's when I've felt the sexiest.

"I've been in both submissive and dominant roles because I want more."

The energetic star divorced Billy Bob last year after three years of marriage.

The wacky couple regularly stunned the showbiz world their outrageous antics including wearing vials of each other's blood around their necks and bragging about their marathon, wild, booze and drug-fuelled sex sessions.

In a bid to quash rumours he had been dumped because he was a cheating love-rat, 48-year-old Thornton told reporters in Cannes earlier this year the marriage broke down because he felt inadequate in comparison with his larger-than-life wife.

Kooky couple ... Angelina and Bob

"It was all down to my inadequacy and fear. I was frightened of Angie because she was too good for me. She was too beautiful, too smart and had too much integrity", he confessed.

Angelina certainly seems to have integrity. The vivacious vixen told Allure she had not been having an affair with Mr and Mrs Smith co-star Brad Pitt because he was a "married man".

"I wouldn't sleep with a married man. I have enough lovers. I don't need Brad", she quipped.

She was a little more philosophical about why she and sexy Irish actor Colin Farrell could never be more than just good friends.

"The reason Colin and I haven't become a couple is that we are the same person. There'd be nobody to ground us. We'd just be nuts," she said.

It seems to have been a busy few months for Angelina out of the bedroom too. As well as starring as a brave fighter pilot with an eye patch in a new blockbuster, Sky Captain and the World of Tomorrow and being voted Esquire magazine's sexiest woman alive, she has also become a mother for the second time.

The star adopted a baby boy on a secret trip to Moscow after a week visiting orphanages in the Russian capital.

Already mother to adopted Cambodian son Maddox, the actress fell for seven-month-old Gleb and according to British website Ananova will return to Moscow for a series of adoption hearings.

NEWS.com.au